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김영삼

Kim, Yung Sam
Ultrafast 2D IR Spectroscopy Lab.
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2D IR photon echo study of the anharmonic coupling in the OCN region of phenyl cyanate

Author(s)
Tucker, Matthew J.Kim, Yung SamHochstrasser, Robin M.
Issued Date
2009-02
DOI
10.1016/j.cplett.2009.01.025
URI
https://scholarworks.unist.ac.kr/handle/201301/8838
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=63749101949
Citation
CHEMICAL PHYSICS LETTERS, v.470, no.1-3, pp.80 - 84
Abstract
The vibrations in the OCN stretching region of phenyl cyanate are examined by two-dimensional infrared spectroscopy. In water and THF, these spectra display three diagonal peaks having cross peaks characteristic of anharmonically coupled transitions. The pattern of the spectra is reproduced by coupling of two overtones with the OCN fundamental.
Publisher
ELSEVIER SCIENCE BV
ISSN
0009-2614
Keyword
2-DIMENSIONAL INFRARED-SPECTROSCOPYVIBRATIONAL SPECTROSCOPYLOCAL ENVIRONMENTFERMI RESONANCEALKYL CYANATESHYDROGEN-BONDALPHA-HELIXAMIDE MODESSPECTRABAND

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