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Park, Cheol-Min
Synthetic & Medicinal Chemistry Lab
Research Interests
  • Organic synthesis, medicinal chemistry, chemical biology

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BETA-ALKOXYACRYLATES IN RADICAL CYCLIZATIONS - REMARKABLY EFFICIENT OXACYCLE SYNTHESIS

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Title
BETA-ALKOXYACRYLATES IN RADICAL CYCLIZATIONS - REMARKABLY EFFICIENT OXACYCLE SYNTHESIS
Author
LEE, ETAE, JSLEE, CPark, Cheol-Min
Issue Date
1993-07
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Citation
TETRAHEDRON LETTERS, v.34, no.30, pp.4831 - 4834
Abstract
Beta-alkoxyacrylates were found to be exceptionally efficient radical acceptors in radical-mediated intramolecular cyclizations. For example, reaction of 5-bromo-2-pentanol with ethyl propiolate, tributylstannane-mediated radical cyclization, and hydrolysis yielded (+/-)-(cis-6-methyltetrahydropyran-2-yl)acetic acid, a known component of civet.
URI
https://scholarworks.unist.ac.kr/handle/201301/8577
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0027302923
DOI
10.1016/S0040-4039(00)74101-3
ISSN
0040-4039
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CHM_Journal Papers
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