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Park, Cheol-Min
Synthetic & Medicinal Chemistry Lab
Research Interests
  • Organic synthesis, medicinal chemistry, chemical biology

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Stereoselective Synthesis of Highly Substituted Enamides by an Oxidative Heck Reaction

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Title
Stereoselective Synthesis of Highly Substituted Enamides by an Oxidative Heck Reaction
Author
Liu, YuLi, DanPark, Cheol-Min
Keywords
arylation; cross-coupling; enamides; Heck reaction; palladium
Issue Date
2011
Publisher
WILEY-V C H VERLAG GMBH
Citation
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.50, no.32, pp.7333 - 7336
Abstract
Functionalization of enamides under Heck conditions has been limited to those with unsubstituted vinyl groups. By tuning reaction parameters that allow for the balance between stability and reactivity of reactants, the oxidative Heck cross-coupling to produce highly substituted enamides in good to excellent yields was achieved (see scheme).
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DOI
10.1002/anie.201101550
ISSN
1433-7851
Appears in Collections:
PHY_Journal Papers
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