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- Park, Cheol-Min
- Synthetic and Medicinal Chemistry Lab.
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Expedient Synthesis of Highly Substituted Pyrroles via Tandem Rearrangement of alpha-Diazo Oxime Ethers
- Author(s)
- Jiang, Yaojia, Chan, Wei Chuen, Park, Cheol-Min
- Issued Date
- 2012-03
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.134, no.9, pp.4104 - 4107
- Abstract
- An efficient rhodium-catalyzed synthesis of 2H-azirines and pyrroles has been developed. Novel rearrangement of α-oximino ketenes derived from α-diazo oxime ethers provides 2H-azirines bearing quaternary centers and allows for subsequent rearrangement to highly substituted pyrroles in excellent yields.
- Publisher
- AMER CHEMICAL SOC
- ISSN
- 0002-7863
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