Synthesis of Pyridines by Carbenoid-Mediated Ring Opening of 2H-Azirines
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- Title
- Synthesis of Pyridines by Carbenoid-Mediated Ring Opening of 2H-Azirines
- Author
- Loy, Nicole S. Y.; Singh, Alok; Xu, Xianxiu; Park, Cheol-Min
- Issue Date
- 2013-02
- Publisher
- WILEY-V C H VERLAG GMBH
- Citation
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.52, no.8, pp.2212 - 2216
- Abstract
- Roaming the range: The title reaction tolerates a wide range of substituents on the resulting pyridine ring using mild reaction conditions (see scheme; esp=α,α,α′,α′-tetramethyl-1,3- benzenedipropionic acid). The formation of the key intermediate is catalyst-controlled, and subsequent cyclization and oxidation affords pyridines in excellent yields. The method has been used for the efficient synthesis of polyarylpyridines.
- URI
- https://scholarworks.unist.ac.kr/handle/201301/8536
- URL
- http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84873909860
- DOI
- 10.1002/anie.201209301
- ISSN
- 1433-7851
- Appears in Collections:
- CHM_Journal Papers
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