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- Park, Cheol-Min
- Synthetic and Medicinal Chemistry Lab.
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Carbenoid-mediated N-O bond insertion and its application in the synthesis of pyridines
- Author(s)
- Qi, Xinxin, Dai, Lu, Park, Cheol-Min
- Issued Date
- 2012-10
- Citation
- CHEMICAL COMMUNICATIONS, v.48, no.91, pp.11244 - 11246
- Abstract
- Highly efficient synthesis of 3-hydroxypyridines has been developed based on carbenoid-mediated N-O bond insertion. Treatment of δ-diazo oxime ethers with dirhodium complex Rh2(tfacam)4 rapidly provides a variety of pyridines in 5-10 minutes in good to excellent yields.
- Publisher
- ROYAL SOC CHEMISTRY
- ISSN
- 1359-7345
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