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Park, Cheol-Min
Synthetic & Medicinal Chemistry Lab
Research Interests
  • Organic synthesis, medicinal chemistry, chemical biology

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Carbenoid-mediated N-O bond insertion and its application in the synthesis of pyridines

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Title
Carbenoid-mediated N-O bond insertion and its application in the synthesis of pyridines
Author
Qi, XinxinDai, LuPark, Cheol-Min
Keywords
DE-NOVO SYNTHESIS; DIELS-ALDER REACTION; ONE-POT SYNTHESIS; DERIVATIVES; CYCLOADDITION; ALKYNES; 1,2,4-TRIAZINES; ISOQUINOLINES; CYCLIZATION; ACETYLENES
Issue Date
2012-10
Publisher
ROYAL SOC CHEMISTRY
Citation
CHEMICAL COMMUNICATIONS, v.48, no.91, pp.11244 - 11246
Abstract
Highly efficient synthesis of 3-hydroxypyridines has been developed based on carbenoid-mediated N-O bond insertion. Treatment of δ-diazo oxime ethers with dirhodium complex Rh2(tfacam)4 rapidly provides a variety of pyridines in 5-10 minutes in good to excellent yields.
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DOI
10.1039/c2cc36009h
ISSN
1359-7345
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PHY_Journal Papers
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