File Download
There are no files associated with this item.
SFX Link
- Find it @ UNIST can give you direct access to the published full text of this article. (UNISTARs only)
- Yoo, Changho
Views & Downloads
Detailed Information
Cited time in 
Cited time in 
Cited time in
Metadata Downloads
AT-Shaped Nickel(I) Metalloradical Species
- Author(s)
- Yoo, Changho, Lee, Yunho
- Issued Date
- 2017-08
- Citation
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.32, pp.9502 - 9506
- Abstract
- A T-shaped Ni-I complex was synthesized using a rigid acridane-based pincer ligand to prepare a metalloradical center. Structural data displays a nickel ion is embedded in the plane of a PNP ligand. Having a sterically exposed half-filled d(x2-y2) orbital, this three-coordinate Ni-I species reveals unique open-shell reactivity including the homolytic cleavage of various sigma-bonds, such as H-H, N-N, and C-C.
- Publisher
- WILEY-V C H VERLAG GMBH
- ISSN
- 1433-7851
- Keyword (Author)
- C-C bond activation, metalloradicals, nickel, radicals
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.