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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 9506 | - |
dc.citation.number | 32 | - |
dc.citation.startPage | 9502 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 56 | - |
dc.contributor.author | Yoo, Changho | - |
dc.contributor.author | Lee, Yunho | - |
dc.date.accessioned | 2023-12-21T21:48:31Z | - |
dc.date.available | 2023-12-21T21:48:31Z | - |
dc.date.created | 2023-09-05 | - |
dc.date.issued | 2017-08 | - |
dc.description.abstract | A T-shaped Ni-I complex was synthesized using a rigid acridane-based pincer ligand to prepare a metalloradical center. Structural data displays a nickel ion is embedded in the plane of a PNP ligand. Having a sterically exposed half-filled d(x2-y2) orbital, this three-coordinate Ni-I species reveals unique open-shell reactivity including the homolytic cleavage of various sigma-bonds, such as H-H, N-N, and C-C. | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.32, pp.9502 - 9506 | - |
dc.identifier.doi | 10.1002/anie.201704487 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.scopusid | 2-s2.0-85025840582 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/65367 | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/10.1002/anie.201704487 | - |
dc.identifier.wosid | 000406385200047 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | AT-Shaped Nickel(I) Metalloradical Species | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | C-C bond activation | - |
dc.subject.keywordAuthor | metalloradicals | - |
dc.subject.keywordAuthor | nickel | - |
dc.subject.keywordAuthor | radicals | - |
dc.subject.keywordPlus | CARBON BOND-CLEAVAGE | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | 3-COORDINATE | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | N-2 | - |
dc.subject.keywordPlus | ACETONITRILE | - |
dc.subject.keywordPlus | ELUCIDATION | - |
dc.subject.keywordPlus | REACTIVITY | - |
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