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Schultz, Thomas
CRASY (Correlated Rotational Alignment Spectroscopy)
Research Interests
  • Correlated spectroscopy
  • Ultrafast spectroscopy
  • High-resolution spectroscopy
  • Photochemistry

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Two-photon photoelectron spectrum of methyl iodide through a dissociative intermediate state

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Title
Two-photon photoelectron spectrum of methyl iodide through a dissociative intermediate state
Author
Schultz, ThomasFischer, I
Keywords
PHOTODISSOCIATION DYNAMICS; MULTIPHOTON IONIZATION; 2-PHOTON IONIZATION; ENERGY; CH3I; SPECTROSCOPY; MOLECULES; ENHANCEMENT; LIFETIMES
Issue Date
1997-10
Publisher
AMER CHEMICAL SOC
Citation
JOURNAL OF PHYSICAL CHEMISTRY A, v.101, no.28, pp.5031 - 5034
Abstract
The two-photon photoelectron spectrum of methyl iodide was recorded in a magnetic bottle time-of-flight spectrometer. As absorption of the first photon is resonant with the dissociative A-state continuum of methyl iodide, the experiment corresponds to a bound-free-bound transition. A progression in the C-I stretching vibration is observed, which corresponds, in a simplified picture, to the dissociation coordinate. The results agree well with recently published two-photon ZEKE spectra of CH3I. This similarity has impact on an ongoing discussion about discrepancies between calculated and measured intensities in two-photon ionization spectra.
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DOI
10.1021/jp971001p
ISSN
1089-5639
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PHY_Journal Papers
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