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Schultz, Thomas
CRASY (Correlated Rotational Alignment Spectroscopy)
Research Interests
  • Correlated spectroscopy
  • Ultrafast spectroscopy
  • High-resolution spectroscopy
  • Photochemistry


Two-photon photoelectron spectrum of methyl iodide through a dissociative intermediate state

DC Field Value Language Schultz, Thomas ko Fischer, I ko 2014-09-23T07:01:56Z - 2014-09-18 ko 1997-10 ko
dc.identifier.citation JOURNAL OF PHYSICAL CHEMISTRY A, v.101, no.28, pp.5031 - 5034 ko
dc.identifier.issn 1089-5639 ko
dc.identifier.uri -
dc.description.abstract The two-photon photoelectron spectrum of methyl iodide was recorded in a magnetic bottle time-of-flight spectrometer. As absorption of the first photon is resonant with the dissociative A-state continuum of methyl iodide, the experiment corresponds to a bound-free-bound transition. A progression in the C-I stretching vibration is observed, which corresponds, in a simplified picture, to the dissociation coordinate. The results agree well with recently published two-photon ZEKE spectra of CH3I. This similarity has impact on an ongoing discussion about discrepancies between calculated and measured intensities in two-photon ionization spectra. ko
dc.description.statementofresponsibility close -
dc.language 영어 ko
dc.publisher AMER CHEMICAL SOC ko
dc.title Two-photon photoelectron spectrum of methyl iodide through a dissociative intermediate state ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-0000295824 ko
dc.identifier.wosid A1997XK23900002 ko
dc.type.rims ART ko
dc.description.wostc 11 *
dc.description.scopustc 10 * 2015-05-06 * 2014-09-18 *
dc.identifier.doi 10.1021/jp971001p ko
dc.identifier.url ko
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