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Cho, Jaephil
Nano Energy Storage Materials Lab (NESM)
Research Interests
  • Li-ion battery, metal-air battery, redox-flow battery, flexible battery .

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Sodium-Decorated Amorphous/Crystalline RuO2 with Rich Oxygen Vacancies: A Robust pH-Universal Oxygen Evolution Electrocatalyst

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Title
Sodium-Decorated Amorphous/Crystalline RuO2 with Rich Oxygen Vacancies: A Robust pH-Universal Oxygen Evolution Electrocatalyst
Author
Zhang, LijieJang, HaeseongLiu, HuihuiKim, Min GyuYang, DongjiangLiu, ShangguoLiu, XienCho, Jaephil
Issue Date
2021-08
Publisher
WILEY-V C H VERLAG GMBH
Citation
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.60, no.34, pp.18821 - 18829
Abstract
The oxygen evolution reaction (OER) is a key reaction for many electrochemical devices. To date, many OER electrocatalysts function well in alkaline media, but exhibit poor performances in neutral and acidic media, especially the acidic stability. Herein, sodium-decorated amorphous/crystalline RuO2 with rich oxygen vacancies (a/c-RuO2) was developed as a pH-universal OER electrocatalyst. The a/c-RuO2 shows remarkable resistance to acid corrosion and oxidation during OER, which leads to an extremely high catalytic stability, as confirmed by a negligible overpotential increase after continuously catalyzing OER for 60 h at pH=1. Besides, a/c-RuO2 also exhibits superior OER activities to commercial RuO2 and most reported OER catalysts under all pH conditions. Theoretical calculations indicated that the introduction of Na dopant and oxygen vacancy in RuO2 weakens the adsorption strength of the OER intermediates by engineering the d-band center, thereby lowering the energy barrier for OER.
URI
https://scholarworks.unist.ac.kr/handle/201301/53425
URL
https://onlinelibrary.wiley.com/doi/10.1002/anie.202106631
DOI
10.1002/anie.202106631
ISSN
1433-7851
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