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- Cho, Jaeheung
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Nucleophilic reactivity of copper(II)-alkylperoxo complexes
- Author(s)
- Kim, Bohee, Jeong, Donghyun, Cho, Jaeheung
- Issued Date
- 2017-08
- Citation
- CHEMICAL COMMUNICATIONS, v.53, no.67, pp.9328 - 9331
- Abstract
- Copper(II)-alkylperoxo adducts, [Cu(CHDAP)(OOR)](+) (CHDAP = N, N'-dicyclohexyl-2,11-diaza[3,3](2,6)pyridinophane; R = C(CH3)(2)Ph and tBu), were prepared and characterized using various physicochemical methods. These are the first synthetic Cu(II)-alkylperoxo complexes that can perform aldehyde deformylation (i.e., nucleophilic reactivity) under the stoichiometric reaction conditions, which was confirmed by kinetic studies.
- Publisher
- ROYAL SOC CHEMISTRY
- ISSN
- 1359-7345
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