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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 9331 | - |
dc.citation.number | 67 | - |
dc.citation.startPage | 9328 | - |
dc.citation.title | CHEMICAL COMMUNICATIONS | - |
dc.citation.volume | 53 | - |
dc.contributor.author | Kim, Bohee | - |
dc.contributor.author | Jeong, Donghyun | - |
dc.contributor.author | Cho, Jaeheung | - |
dc.date.accessioned | 2023-12-21T21:49:13Z | - |
dc.date.available | 2023-12-21T21:49:13Z | - |
dc.date.created | 2020-09-03 | - |
dc.date.issued | 2017-08 | - |
dc.description.abstract | Copper(II)-alkylperoxo adducts, [Cu(CHDAP)(OOR)](+) (CHDAP = N, N'-dicyclohexyl-2,11-diaza[3,3](2,6)pyridinophane; R = C(CH3)(2)Ph and tBu), were prepared and characterized using various physicochemical methods. These are the first synthetic Cu(II)-alkylperoxo complexes that can perform aldehyde deformylation (i.e., nucleophilic reactivity) under the stoichiometric reaction conditions, which was confirmed by kinetic studies. | - |
dc.identifier.bibliographicCitation | CHEMICAL COMMUNICATIONS, v.53, no.67, pp.9328 - 9331 | - |
dc.identifier.doi | 10.1039/c7cc03965d | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.scopusid | 2-s2.0-85027550211 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/48106 | - |
dc.identifier.url | https://pubs.rsc.org/en/content/articlelanding/2017/CC/C7CC03965D#!divAbstract | - |
dc.identifier.wosid | 000407808000009 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Nucleophilic reactivity of copper(II)-alkylperoxo complexes | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | III-OOR COMPLEXES | - |
dc.subject.keywordPlus | O BOND-CLEAVAGE | - |
dc.subject.keywordPlus | HIGH-SPIN IRON(III)-ALKYLPEROXO | - |
dc.subject.keywordPlus | NONHEME IRON MODELS | - |
dc.subject.keywordPlus | SUPEROXIDE REDUCTASE | - |
dc.subject.keywordPlus | ELECTRONIC-STRUCTURE | - |
dc.subject.keywordPlus | COORDINATION SPHERE | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | MECHANISM | - |
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