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- Grzybowski, Bartosz A.
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Chromatography in a Single Metal-Organic Framework (MOF) Crystal
- Author(s)
- Han, Shuangbing, Wei, Yanhu, Valente, Cory, Lagzi, Istvan, Gassensmith, Jeremiah J., Coskun, Ali, Stoddart, J. Fraser, Grzybowski, Bartosz A.
- Issued Date
- 2010-11
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.132, no.46, pp.16358 - 16361
- Abstract
- Millimeter-sized single MOF-5 crystals are used as "chromatographic columns" to effectively separate mixtures of organic dyes. Remarkably, owing to the nanoscopic pore dimensions and the molecular-level interactions between the migrating molecules and the MOF scaffold, the separations occur over a distance of only a few hundred micrometers which is unambiguously confirmed by fluorescence confocal microscopy.
- Publisher
- AMER CHEMICAL SOC
- ISSN
- 0002-7863
- Keyword
- XYLENE ISOMERS, SEPARATION, ADSORPTION, PERFORMANCE, SELECTIVITY, FILMS, THIN
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