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- Park, Noejung
- Computational Physics & Electronic Structure Lab.
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Postsynthetic Exchanges of the Pillaring Ligand in Three-Dimensional Metal-Organic Frameworks
- Author(s)
- Jeong, Seok, Kim, Dongwook, Song, Xiaokai, Choi, Min, Park, Noejung, Lah, Myoung Soo
- Issued Date
- 2013-04
- Citation
- CHEMISTRY OF MATERIALS, v.25, no.7, pp.1047 - 1054
- Abstract
- Metal-organic frameworks, [Ni(HBTC) (dabco)] (2) and [Ni-2(HBTC)(2)(bipy)(0.6)(dabco)(1.4)] (3) (where H3BTC is 1,3,5-benzenetricarboxylic acid, dabco is 1,4-diazabicyclo[2.2.2]octane, and bipy is 4,4'-bipyridine), were prepared via postsynthetic ligand exchanges of [Ni(HBTC)(bipy)] (1). By controlling the concentration of dabco, we could obtain not only entropically favorable 2 with completely exchanged dabco but also enthalpically favorable 3 with selectively exchanged bipy/dabco in the alternating layers.
- Publisher
- AMER CHEMICAL SOC
- ISSN
- 0897-4756
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