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Park, Noejung
Computational Physics & Electronic Structure Lab.
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dc.citation.endPage 1054 -
dc.citation.number 7 -
dc.citation.startPage 1047 -
dc.citation.title CHEMISTRY OF MATERIALS -
dc.citation.volume 25 -
dc.contributor.author Jeong, Seok -
dc.contributor.author Kim, Dongwook -
dc.contributor.author Song, Xiaokai -
dc.contributor.author Choi, Min -
dc.contributor.author Park, Noejung -
dc.contributor.author Lah, Myoung Soo -
dc.date.accessioned 2023-12-22T04:08:54Z -
dc.date.available 2023-12-22T04:08:54Z -
dc.date.created 2013-07-04 -
dc.date.issued 2013-04 -
dc.description.abstract Metal-organic frameworks, [Ni(HBTC) (dabco)] (2) and [Ni-2(HBTC)(2)(bipy)(0.6)(dabco)(1.4)] (3) (where H3BTC is 1,3,5-benzenetricarboxylic acid, dabco is 1,4-diazabicyclo[2.2.2]octane, and bipy is 4,4'-bipyridine), were prepared via postsynthetic ligand exchanges of [Ni(HBTC)(bipy)] (1). By controlling the concentration of dabco, we could obtain not only entropically favorable 2 with completely exchanged dabco but also enthalpically favorable 3 with selectively exchanged bipy/dabco in the alternating layers. -
dc.identifier.bibliographicCitation CHEMISTRY OF MATERIALS, v.25, no.7, pp.1047 - 1054 -
dc.identifier.doi 10.1021/cm303624p -
dc.identifier.issn 0897-4756 -
dc.identifier.scopusid 2-s2.0-84875970567 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/3279 -
dc.identifier.url http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84875970567 -
dc.identifier.wosid 000317438600005 -
dc.language 영어 -
dc.publisher AMER CHEMICAL SOC -
dc.title Postsynthetic Exchanges of the Pillaring Ligand in Three-Dimensional Metal-Organic Frameworks -
dc.type Article -
dc.relation.journalWebOfScienceCategory Chemistry, Physical; Materials Science, Multidisciplinary -
dc.relation.journalResearchArea Chemistry; Materials Science -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -
dc.subject.keywordAuthor metal-organic frameworks (MOFs) -
dc.subject.keywordAuthor postsynthetic modification (PSM) -
dc.subject.keywordAuthor postsynthetic ligand exchange (PSLE) -
dc.subject.keywordAuthor enthalpically favorable exchange -
dc.subject.keywordAuthor entropically favorable exchange -
dc.subject.keywordAuthor gas sorption -
dc.subject.keywordAuthor adsorption enthalpy -
dc.subject.keywordPlus TOTAL-ENERGY CALCULATIONS -
dc.subject.keywordPlus WAVE BASIS-SET -
dc.subject.keywordPlus HYDROGEN STORAGE -
dc.subject.keywordPlus ION-EXCHANGE -
dc.subject.keywordPlus FUNCTIONALIZATION -
dc.subject.keywordPlus CONSTRUCTION -
dc.subject.keywordPlus SORPTION -

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