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Low-temperature single-wall carbon nanotubes synthesis: Feedstock decomposition limited growth

Author(s)
Mora, ElenaPigos, John M.Ding, FengYakobson, Boris I.Harutyunyan, Avetik R.
Issued Date
2008-09
DOI
10.1021/ja8035724
URI
https://scholarworks.unist.ac.kr/handle/201301/31404
Fulltext
https://pubs.acs.org/doi/10.1021/ja8035724
Citation
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.130, no.36, pp.11840 - 11841
Abstract
We report on the lowest temperature of SWCNT growth using endothermic decomposition of CH4 gas on a specially activated alumina-supported Fe:Mo catalyst. However, the observed lowest growth temperature (560 °C) is higher than that reported previously for exothermic feedstock type. Our observation indicates that the decomposition threshold temperature of the feedstock limits the SWCNT growth. This study also suggests that, by using more active carbon feedstock or somehow facilitating its decomposition, one could enable the synthesis of SWCNT at an even lower temperature.
Publisher
AMER CHEMICAL SOC
ISSN
0002-7863
Keyword
CHEMICAL-VAPOR-DEPOSITIONCVD SYNTHESISNUCLEATIONSTATE

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