Low-temperature single-wall carbon nanotubes synthesis: Feedstock decomposition limited growth

Abstract

We report on the lowest temperature of SWCNT growth using endothermic decomposition of CH4 gas on a specially activated alumina-supported Fe:Mo catalyst. However, the observed lowest growth temperature (560 °C) is higher than that reported previously for exothermic feedstock type. Our observation indicates that the decomposition threshold temperature of the feedstock limits the SWCNT growth. This study also suggests that, by using more active carbon feedstock or somehow facilitating its decomposition, one could enable the synthesis of SWCNT at an even lower temperature.