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Park, Jaeyeong
Fuel Cycle and Waste Laboratory
Research Interests
  • Radioactive waste treatment and management; Spent nuclear fuel recycling; Decontamination and Decommissioning; Nuclear Fuel Cycle

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Cyclic Voltammetry on CeCl3 in LiCl-KCl Eutectic Using W and Bi Coated Electrode

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Title
Cyclic Voltammetry on CeCl3 in LiCl-KCl Eutectic Using W and Bi Coated Electrode
Author
Sohn, SungjunePark, JaeyeongKim, Pyeong-HwaHwang, Il Soon
Issue Date
2016
Publisher
Elsevier
Citation
PROCEDIA CHEMISTRY, v.21, pp.401 - 408
Abstract
This paper presents experimental results of cyclic voltammetry on CeCl3 in LiCl-KCl using tungsten electrode and Bi coated electrode respectively at 703K. Using tungsten electrode at low concentration of CeCl3, the redox reaction has been shown to be reversible. Diffusion coefficient and apparent standard potential of Ce(III) in LiCl-KCl were 0.42×10-5 (cm2/s) and -3.153 (V vs. Cl2/Cl−) under 50mV/s. In order to obtain Bi coated electrode, cyclic voltammetry was carried out on eutectic salt including BiCl3. The redox reaction of Ce on Bi coated electrode has been shown to be reversible and apparent standard potential on Bi coated electrode moved 782mV compared with tungsten cathode.
URI
https://scholarworks.unist.ac.kr/handle/201301/22953
URL
http://www.sciencedirect.com/science/article/pii/S1876619616300985
DOI
10.1016/j.proche.2016.10.056
ISSN
1876-6196
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