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Moon, Hoi Ri
Functional Inorganic Nanomaterials Lab for Energy
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Topology Conversions of Non-Interpenetrated Metal-Organic Frameworks to Doubly Interpenetrated Metal-Organic Frameworks

Author(s)
Jeong, SeokKim, DongwookPark, JeonginShin, SunyoungKim, HyehyunJeong, Gyoung HwaMoon, DohyunMoon, Hoi RiLah, Myoung Soo
Issued Date
2017-05
DOI
10.1021/acs.chemmater.6b05277
URI
https://scholarworks.unist.ac.kr/handle/201301/22292
Fulltext
http://pubs.acs.org/doi/abs/10.1021/acs.chemmater.6b05277
Citation
CHEMISTRY OF MATERIALS, v.29, no.9, pp.3899 - 3907
Abstract
Non-interpenetrated three-dimensional (3D) metal-organic frameworks (MOFs) with both an interpenetration-favorable (3,5)-c hms topology and an interpenetration-unfavorable (3,5)-c gra topology are converted to doubly interpenetrated analogues with hmsc topology by thermal treatment, even in the absence of solvent. Depending on the conversion temperature and the properties of the pillaring ligand in the non-interpenetrated 3D MOF, which is based on two-dimensional sheets with 3-c hcb topology pillared by neutral ditopic linkers, the pillaring ligands in the interpenetrated MOFs produced are partially removed during the thermal conversions, leading to interpenetrated MOFs that simultaneously contain both micro- and mesopores.
Publisher
AMER CHEMICAL SOC
ISSN
0897-4756
Keyword
INORGANIC 3D NETWORKSULTRAHIGH POROSITYSINGLE-CRYSTALSURFACE-AREACATENATIONNETSDATABASELIGANDCHEMISTRYEXCHANGE

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