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- Bielawski, Christopher W.
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Diamidocarbene Induced B-H Activation: A New Class of Initiator-Free Olefin Hydroboration Reagents
- Issued Date
- 2016-03
- Citation
- ORGANOMETALLICS, v.35, no.5, pp.706 - 712
- Abstract
- Enabled by its enhanced electrophilicity and attenuated nucleophilicity, an N,N'-diamidocarbene (DAC) was found to promote the B-H bond activation of various BH3 complexes and the B-B bond of bis(pinacolato)diboron, constituting the first such examples for an isolable carbene. The resultant DAC-BH3 adducts datively coordinated to Lewis bases (i.e., dimethyl sulfide, trimethylamine, or pyridine) and facilitated the hydroboration of various olefins under mild conditions and in the absence of exogenous initiators.
- Publisher
- AMER CHEMICAL SOC
- ISSN
- 0276-7333
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