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- Bielawski, Christopher W.
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| DC Field | Value | Language |
|---|---|---|
| dc.citation.endPage | 712 | - |
| dc.citation.number | 5 | - |
| dc.citation.startPage | 706 | - |
| dc.citation.title | ORGANOMETALLICS | - |
| dc.citation.volume | 35 | - |
| dc.contributor.author | Lastovickova, Dominika N. | - |
| dc.contributor.author | Bielawski, Christopher W. | - |
| dc.date.accessioned | 2023-12-22T00:07:24Z | - |
| dc.date.available | 2023-12-22T00:07:24Z | - |
| dc.date.created | 2016-05-03 | - |
| dc.date.issued | 2016-03 | - |
| dc.description.abstract | Enabled by its enhanced electrophilicity and attenuated nucleophilicity, an N,N'-diamidocarbene (DAC) was found to promote the B-H bond activation of various BH3 complexes and the B-B bond of bis(pinacolato)diboron, constituting the first such examples for an isolable carbene. The resultant DAC-BH3 adducts datively coordinated to Lewis bases (i.e., dimethyl sulfide, trimethylamine, or pyridine) and facilitated the hydroboration of various olefins under mild conditions and in the absence of exogenous initiators. | - |
| dc.identifier.bibliographicCitation | ORGANOMETALLICS, v.35, no.5, pp.706 - 712 | - |
| dc.identifier.doi | 10.1021/acs.organomet.5b00997 | - |
| dc.identifier.issn | 0276-7333 | - |
| dc.identifier.scopusid | 2-s2.0-84961124875 | - |
| dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/19073 | - |
| dc.identifier.url | http://pubs.acs.org/doi/abs/10.1021/acs.organomet.5b00997 | - |
| dc.identifier.wosid | 000372210300013 | - |
| dc.language | 영어 | - |
| dc.publisher | AMER CHEMICAL SOC | - |
| dc.title | Diamidocarbene Induced B-H Activation: A New Class of Initiator-Free Olefin Hydroboration Reagents | - |
| dc.type | Article | - |
| dc.description.isOpenAccess | FALSE | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear; Chemistry, Organic | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.subject.keywordPlus | N-HETEROCYCLIC CARBENE | - |
| dc.subject.keywordPlus | CHEMICAL-SHIFTS | - |
| dc.subject.keywordPlus | CATALYZED HYDROBORATION | - |
| dc.subject.keywordPlus | BOND ACTIVATION | - |
| dc.subject.keywordPlus | AMINE-BORANES | - |
| dc.subject.keywordPlus | REACTIVITY | - |
| dc.subject.keywordPlus | HYDROGEN | - |
| dc.subject.keywordPlus | ADDUCTS | - |
| dc.subject.keywordPlus | AMMONIA | - |
| dc.subject.keywordPlus | DERIVATIVES | - |
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