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Hong, Sung You
Synthetic Organic Chemistry Laboratory
Research Interests
  • Synthetic organic chemistry, transition metals, oxidation state

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Copper-Catalyzed Direct Synthesis of 1,2,4-Oxadiazoles from Amides and Organic Nitriles by Oxidative N-O Bond Formation

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Title
Copper-Catalyzed Direct Synthesis of 1,2,4-Oxadiazoles from Amides and Organic Nitriles by Oxidative N-O Bond Formation
Author
Kuram, Malleswara RaoKim, Woo GyumMyung, KyungjaeHong, Sung You
Issue Date
2016-01
Publisher
WILEY-V C H VERLAG GMBH
Citation
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v.2016, no.3, pp.438 - 442
Abstract
Herein, we report the first Cu-catalyzed one-step method for the synthesis of 1,2,4-oxadiazoles from stable, less toxic, and readily available amides and organic nitriles by a rare oxidative N-O bond formation using O2 as sole oxidant. This method has a broad substrate scope and a good tolerance for diverse functional groups. Moreover, the synthetic utility of this method is highlighted by the synthesis of biologically active 3,5-disubstituted derivatives.
URI
https://scholarworks.unist.ac.kr/handle/201301/18046
URL
http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201501502/abstract;jsessionid=6411E187B67E25916AA5444AA6C53AE4.f03t04
DOI
10.1002/ejoc.201501502
ISSN
1434-193X
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CHM_Journal Papers
BME_Journal Papers
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