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Lee, Jae Sung
Eco-friendly Catalysis and Energy Lab
Research Interests
  • Photocatalytic water splitting, artificial photosynthesis, fuel cells, heterogeneous catalysis

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The effects of reaction variables on the palladium-catalyzed reactions of butadiene with water

Cited 10 times inthomson ciCited 9 times inthomson ci
Title
The effects of reaction variables on the palladium-catalyzed reactions of butadiene with water
Other Titles
The effects of reaction variables on the palladium-catalyzed reactions of butadiene with water
Author
Lee, Byoung InLee, Kyung HeeLee, Jae Sung
Keywords
butadiene; water; octadienol; telomerization; cyclodimerization; palladium catalysts; reaction variables
Issue Date
2001-02
Publisher
ELSEVIER SCIENCE BV
Citation
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, v.166, no.2, pp.233 - 242
Abstract
The effects of reaction variables on the reactions of butadiene with water in the presence of homogeneous palladium catalysts were investigated. The reactions in the presence of palladium, a phosphine ligand and carbon dioxide comprized telomerization, linear dimerization and cyclodimerization. The rate of reaction and the selectivity to 2,7-octadien-1-ol, 1,3,7-octatriene and 1-methylene 2-vinyl cyclopentane depended strongly upon the ratio of water to butadiene, the ratio of phosphine to palladium, the amount of carbon dioxide and the reaction time. 2,7-Octadien-1-ol that formed initially was subsequently converted to a mixture of 1,7-octadien-3-ol, 1,3,7-octatriene and 1-methylene-2-vinyl cyclopentane, the degree of which depended on the reaction conditions, A possible reaction pathway for the reaction of butadiene with water has been proposed. (C) 2001 Elsevier Science B.V. All rights reserved
URI
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DOI
10.1016/S1381-1169(00)00444-1
ISSN
1381-1169
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ECHE_Journal Papers
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