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Lee, Jae Sung
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dc.citation.endPage 242 -
dc.citation.number 2 -
dc.citation.startPage 233 -
dc.citation.title JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL -
dc.citation.volume 166 -
dc.contributor.author Lee, Byoung In -
dc.contributor.author Lee, Kyung Hee -
dc.contributor.author Lee, Jae Sung -
dc.date.accessioned 2023-12-22T12:06:03Z -
dc.date.available 2023-12-22T12:06:03Z -
dc.date.created 2015-07-27 -
dc.date.issued 2001-02 -
dc.description.abstract The effects of reaction variables on the reactions of butadiene with water in the presence of homogeneous palladium catalysts were investigated. The reactions in the presence of palladium, a phosphine ligand and carbon dioxide comprized telomerization, linear dimerization and cyclodimerization. The rate of reaction and the selectivity to 2,7-octadien-1-ol, 1,3,7-octatriene and 1-methylene 2-vinyl cyclopentane depended strongly upon the ratio of water to butadiene, the ratio of phosphine to palladium, the amount of carbon dioxide and the reaction time. 2,7-Octadien-1-ol that formed initially was subsequently converted to a mixture of 1,7-octadien-3-ol, 1,3,7-octatriene and 1-methylene-2-vinyl cyclopentane, the degree of which depended on the reaction conditions, A possible reaction pathway for the reaction of butadiene with water has been proposed. (C) 2001 Elsevier Science B.V. All rights reserved -
dc.identifier.bibliographicCitation JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, v.166, no.2, pp.233 - 242 -
dc.identifier.doi 10.1016/S1381-1169(00)00444-1 -
dc.identifier.issn 1381-1169 -
dc.identifier.scopusid 2-s2.0-0035865461 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/12684 -
dc.identifier.url http://www.sciencedirect.com/science/article/pii/S1381116900004441# -
dc.identifier.wosid 000167082900005 -
dc.language 영어 -
dc.publisher ELSEVIER SCIENCE BV -
dc.title.alternative The effects of reaction variables on the palladium-catalyzed reactions of butadiene with water -
dc.title The effects of reaction variables on the palladium-catalyzed reactions of butadiene with water -
dc.type Article -
dc.description.journalRegisteredClass scopus -

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