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DC Field | Value | Language |
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dc.citation.endPage | 242 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | 233 | - |
dc.citation.title | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | - |
dc.citation.volume | 166 | - |
dc.contributor.author | Lee, Byoung In | - |
dc.contributor.author | Lee, Kyung Hee | - |
dc.contributor.author | Lee, Jae Sung | - |
dc.date.accessioned | 2023-12-22T12:06:03Z | - |
dc.date.available | 2023-12-22T12:06:03Z | - |
dc.date.created | 2015-07-27 | - |
dc.date.issued | 2001-02 | - |
dc.description.abstract | The effects of reaction variables on the reactions of butadiene with water in the presence of homogeneous palladium catalysts were investigated. The reactions in the presence of palladium, a phosphine ligand and carbon dioxide comprized telomerization, linear dimerization and cyclodimerization. The rate of reaction and the selectivity to 2,7-octadien-1-ol, 1,3,7-octatriene and 1-methylene 2-vinyl cyclopentane depended strongly upon the ratio of water to butadiene, the ratio of phosphine to palladium, the amount of carbon dioxide and the reaction time. 2,7-Octadien-1-ol that formed initially was subsequently converted to a mixture of 1,7-octadien-3-ol, 1,3,7-octatriene and 1-methylene-2-vinyl cyclopentane, the degree of which depended on the reaction conditions, A possible reaction pathway for the reaction of butadiene with water has been proposed. (C) 2001 Elsevier Science B.V. All rights reserved | - |
dc.identifier.bibliographicCitation | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, v.166, no.2, pp.233 - 242 | - |
dc.identifier.doi | 10.1016/S1381-1169(00)00444-1 | - |
dc.identifier.issn | 1381-1169 | - |
dc.identifier.scopusid | 2-s2.0-0035865461 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/12684 | - |
dc.identifier.url | http://www.sciencedirect.com/science/article/pii/S1381116900004441# | - |
dc.identifier.wosid | 000167082900005 | - |
dc.language | 영어 | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.title.alternative | The effects of reaction variables on the palladium-catalyzed reactions of butadiene with water | - |
dc.title | The effects of reaction variables on the palladium-catalyzed reactions of butadiene with water | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
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