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Lee, Jae Sung
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COMMENTS ON THE MECHANISM OF OXIDATIVE COUPLING OF METHANE

Alternative Title
COMMENTS ON THE MECHANISM OF OXIDATIVE COUPLING OF METHANE
Author(s)
Lee, Jae SungOYAMA, S.Ted
Issued Date
1990-05
DOI
10.1007/BF02097878
URI
https://scholarworks.unist.ac.kr/handle/201301/12548
Fulltext
http://link.springer.com/article/10.1007%2FBF02097878
Citation
REACTION KINETICS AND CATALYSIS LETTERS, v.41, no.2, pp.257 - 263
Abstract
Fundamental aspects of the mechanism of oxidative methane coupling are treated. The surface has a dual role. In the selective pathway to C2 products it generates methyl radicals which leave the surface to recombine in the gas phase. In the non-selective pathway to COx it catalyzes the oxidation of surface methyl species or C2 products that return to the surface. This mechanism leads to research strategies for selectivity improvement. © 1990 Akadémiai Kiadó.
Publisher
Akademiai Kiado
ISSN
0133-1736

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