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Tuning chirality of single-wall carbon nanotubes by selective etching with carbon dioxide

Alternative Title
Tuning Chirality of Single-Wall Carbon Nanotubes by Selective Etching with Carbon Dioxide
Author(s)
Seo, KwanyongKim, ChangwookChoi, Yong SooPark, Kyung AhLee, Young HeeKim, Bongsoo
Issued Date
2003-11
DOI
10.1021/ja035262q
URI
https://scholarworks.unist.ac.kr/handle/201301/12266
Fulltext
http://pubs.acs.org/doi/abs/10.1021/ja035262q
Citation
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.125, no.46, pp.13946 - 13947
Abstract
CO2 molecule chemisorbs selectively on the zigzag tube edge without an activation barrier, whereas it physisorbs on the armchair edge of nanotubes. In addition, carbon nanotubes can be etched by an adsorbed oxygen atom of CO2 molecule. From our results, we suggest a selective etching mechanism for tuning the chirality of the mass-produced carbon nanotubes. Copyright © 2003 American Chemical Society.
Publisher
AMER CHEMICAL SOC
ISSN
0002-7863

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