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Rohde, Jan-Uwe
Transition Metal Chemistry
Research Interests
  • Inorganic chemistry, coordination chemistry, organometallic chemistry, chemical synthesis, catalysis, green chemistry, inorganic reaction mechanisms.

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Axial coordination of carboxylate activates the non-heme Fe-IV = O unit

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Title
Axial coordination of carboxylate activates the non-heme Fe-IV = O unit
Author
Rohde, Jan-UweQue, L
Issue Date
2005-04
Publisher
WILEY-V C H VERLAG GMBH
Citation
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.44, no.15, pp.2255 - 2258
Abstract
Enhancing reactivity: A common feature of non-heme iron enzymes is the presence of carboxylate groups. An axial carboxylate group has been introduced trans to the oxo group of a non-heme oxoiron(iv) complex (see scheme). The coordination of carboxylate destabilizes the FeIV[DOUBLE BOND]O unit and activates it towards reaction with dihydroanthracene.
URI
https://scholarworks.unist.ac.kr/handle/201301/11979
URL
http://onlinelibrary.wiley.com/doi/10.1002/anie.200462631/abstract
DOI
10.1002/anie.200462631
ISSN
1433-7851
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CHM_Journal Papers
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