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- Rohde, Jan-Uwe
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Axial coordination of carboxylate activates the non-heme Fe-IV = O unit
- Author(s)
- Rohde, Jan-Uwe, Que, L
- Issued Date
- 2005-04
- Citation
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.44, no.15, pp.2255 - 2258
- Abstract
- Enhancing reactivity: A common feature of non-heme iron enzymes is the presence of carboxylate groups. An axial carboxylate group has been introduced trans to the oxo group of a non-heme oxoiron(iv) complex (see scheme). The coordination of carboxylate destabilizes the FeIV[DOUBLE BOND]O unit and activates it towards reaction with dihydroanthracene.
- Publisher
- WILEY-V C H VERLAG GMBH
- ISSN
- 1433-7851
- Keyword (Author)
- bioinorganic chemistry, carboxylate ligands, high-valent compounds, iron, oxo ligands
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