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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 2258 | - |
dc.citation.number | 15 | - |
dc.citation.startPage | 2255 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 44 | - |
dc.contributor.author | Rohde, Jan-Uwe | - |
dc.contributor.author | Que, L | - |
dc.date.accessioned | 2023-12-22T10:37:06Z | - |
dc.date.available | 2023-12-22T10:37:06Z | - |
dc.date.created | 2015-07-03 | - |
dc.date.issued | 2005-04 | - |
dc.description.abstract | Enhancing reactivity: A common feature of non-heme iron enzymes is the presence of carboxylate groups. An axial carboxylate group has been introduced trans to the oxo group of a non-heme oxoiron(iv) complex (see scheme). The coordination of carboxylate destabilizes the FeIV[DOUBLE BOND]O unit and activates it towards reaction with dihydroanthracene. | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.44, no.15, pp.2255 - 2258 | - |
dc.identifier.doi | 10.1002/anie.200462631 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.scopusid | 2-s2.0-17644419347 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/11979 | - |
dc.identifier.url | http://onlinelibrary.wiley.com/doi/10.1002/anie.200462631/abstract | - |
dc.identifier.wosid | 000228415900017 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Axial coordination of carboxylate activates the non-heme Fe-IV = O unit | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | bioinorganic chemistry | - |
dc.subject.keywordAuthor | carboxylate ligands | - |
dc.subject.keywordAuthor | high-valent compounds | - |
dc.subject.keywordAuthor | iron | - |
dc.subject.keywordAuthor | oxo ligands | - |
dc.subject.keywordPlus | TAURINE/ALPHA-KETOGLUTARATE DIOXYGENASE | - |
dc.subject.keywordPlus | OXYGEN ACTIVATION | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | IRON | - |
dc.subject.keywordPlus | INTERMEDIATE | - |
dc.subject.keywordPlus | ENZYMES | - |
dc.subject.keywordPlus | HYDROXYLATION | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | BONDS | - |
dc.subject.keywordPlus | TAUD | - |
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