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박철민

Park, Cheol-Min
Synthetic and Medicinal Chemistry Lab.
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Synthesis of unsymmetrical pyrazines based on α-diazo oxime ethers

Author(s)
Loy, Nicole S. Y.Kim, SunggakPark, Cheol-Min
Issued Date
2015-02
DOI
10.1021/ol5034173
URI
https://scholarworks.unist.ac.kr/handle/201301/10758
Fulltext
http://pubs.acs.org/doi/abs/10.1021/ol5034173
Citation
ORGANIC LETTERS, v.17, no.3, pp.395 - 397
Abstract
Synthesis of unsymmetrically substituted pyrazines has been a challenge. The reactivity of α-imino carbenoids derived from α-diazo oxime ethers has been exploited for pyrazine synthesis, in which the reaction of α-diazo oxime ethers with 2H-azirines provides highly substituted pyrazines in good to excellent yields.
Publisher
AMER CHEMICAL SOC
ISSN
1523-7060
Keyword
ACTIVE DEOXYASPERGILLIC ACIDHIGHLY SUBSTITUTED PYRROLESFACILE SYNTHESISENANTIOSELECTIVE SYNTHESISSTEREOSELECTIVE-SYNTHESIS2H-AZIRINESPYRIDINESALKYLPYRAZINESINSERTIONROUTE

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