Synthesis of unsymmetrical pyrazines based on α-diazo oxime ethers
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- Synthesis of unsymmetrical pyrazines based on α-diazo oxime ethers
- Loy, Nicole S. Y.; Kim, Sunggak; Park, Cheol-Min
- Issue Date
- AMER CHEMICAL SOC
- ORGANIC LETTERS, v.17, no.3, pp.395 - 397
- Synthesis of unsymmetrically substituted pyrazines has been a challenge. The reactivity of α-imino carbenoids derived from α-diazo oxime ethers has been exploited for pyrazine synthesis, in which the reaction of α-diazo oxime ethers with 2H-azirines provides highly substituted pyrazines in good to excellent yields.
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