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- Kwon, Oh Hoon
- Ultrafast Laser Spectroscopy and Nano-microscopy Lab.
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Asymmetric double proton transfer of excited 1 : 1 7-azaindole/alcohol complexes with anomalously large and temperature-independent kinetic isotope effects
- Author(s)
- Kwon, Oh Hoon, Lee, YS, Park, HJ, Kim, Y, Jang, DJ
- Issued Date
- 2004
- Citation
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.43, no.43, pp.5792 - 5796
- Abstract
- Bridging alcohols, tunneling protons: The intrinsic proton-transfer dynamics of cyclic H-bonded 1:1 7-azaindole/alcohol complexes in n-alkanes has been investigated at the lowest-lying excited singlet state with variation of alcohol, solvent, isotope, and temperature by using static and time-resolved spectroscopy. The proton transfer occurs asymmetrically, and the rate is governed by tunneling although it is assisted by heavy-atom motions.
- Publisher
- WILEY-V C H VERLAG GMBH
- ISSN
- 1433-7851
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