dc.citation.endPage |
5796 |
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dc.citation.number |
43 |
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dc.citation.startPage |
5792 |
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dc.citation.title |
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION |
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dc.citation.volume |
43 |
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dc.contributor.author |
Kwon, Oh Hoon |
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dc.contributor.author |
Lee, YS |
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dc.contributor.author |
Park, HJ |
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dc.contributor.author |
Kim, Y |
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dc.contributor.author |
Jang, DJ |
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dc.date.accessioned |
2023-12-22T11:07:38Z |
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dc.date.available |
2023-12-22T11:07:38Z |
- |
dc.date.created |
2014-11-13 |
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dc.date.issued |
2004 |
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dc.description.abstract |
Bridging alcohols, tunneling protons: The intrinsic proton-transfer dynamics of cyclic H-bonded 1:1 7-azaindole/alcohol complexes in n-alkanes has been investigated at the lowest-lying excited singlet state with variation of alcohol, solvent, isotope, and temperature by using static and time-resolved spectroscopy. The proton transfer occurs asymmetrically, and the rate is governed by tunneling although it is assisted by heavy-atom motions. |
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dc.identifier.bibliographicCitation |
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.43, no.43, pp.5792 - 5796 |
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dc.identifier.doi |
10.1002/anie.200461102 |
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dc.identifier.issn |
1433-7851 |
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dc.identifier.scopusid |
2-s2.0-8844269438 |
- |
dc.identifier.uri |
https://scholarworks.unist.ac.kr/handle/201301/8793 |
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dc.identifier.url |
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=8844269438 |
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dc.identifier.wosid |
000225204100012 |
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dc.language |
영어 |
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dc.publisher |
WILEY-V C H VERLAG GMBH |
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dc.title |
Asymmetric double proton transfer of excited 1 : 1 7-azaindole/alcohol complexes with anomalously large and temperature-independent kinetic isotope effects |
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dc.type |
Article |
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dc.description.journalRegisteredClass |
scopus |
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