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Lah, Myoung Soo
Frontier Energy Storage Material Lab.
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Preparation of chromium-manganese diarene heterobimetallic complexes using a Mn(CO)(3)(+) transfer reaction

Author(s)
Lee, SSLee, TYLee, Joo EunLee, ISChung, YKLah, Myoung Soo
Issued Date
1996-08
DOI
10.1021/om960189g
URI
https://scholarworks.unist.ac.kr/handle/201301/9903
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0000511032
Citation
ORGANOMETALLICS, v.15, no.17, pp.3664 - 3669
Abstract
The reaction of mono-Cr(CO)(3) complexes of a number of aromatic compounds containing two arene groups with the Mn(CO)(3)(+) transfer agent [(naphthaleneMn(CO)(3)](+) gave new Cr/Mn diarene heterobimetallic compounds, e.g., (OC)(3)Cr(eta(6)-C6H5CH=CHC6H5-eta(6))Mn(CO)(3)(+). This and two others of these compounds were characterized by X-ray diffraction. The two metal carbonyl groups were found to be on the same face of the aromatic hydrocarbon molecules in a syn arrangement.
Publisher
AMER CHEMICAL SOC
ISSN
0276-7333

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