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Schultz, Thomas
CRASY (Correlated Rotational Alignment Spectroscopy)
Research Interests
  • Correlated spectroscopy
  • Ultrafast spectroscopy
  • High-resolution spectroscopy
  • Photochemistry

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Time- and frequency-resolved photoionisation of the allyl radical

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Title
Time- and frequency-resolved photoionisation of the allyl radical
Author
Schultz, ThomasClarke, JSGilbert, TDeyerl, HJFischer, I
Keywords
IONIZATION PHOTOELECTRON-SPECTROSCOPY; ULTRAFAST INTERNAL-CONVERSION; MULTIPHOTON IONIZATION; PHOTODISSOCIATION DYNAMICS; PICOSECOND TIME; EXCITED-STATE; ANGULAR-DISTRIBUTIONS; ELECTRONIC-SPECTRUM; ULTRAVIOLET BANDS; RYDBERG STATES
Issue Date
2000
Publisher
ROYAL SOC CHEMISTRY
Citation
FARADAY DISCUSSIONS, v.115, no., pp.17 - 31
Abstract
We report picosecond time-resolved pump-probe photoelectron spectra of the allyl radical, C3H5, and the fully deuterated allyl, C3D5, carried out in order to elucidate the primary photophysical processes upon UV excitation. It is shown that the UV bands of allyl decay in a two-step process: the first step is an internal conversion to the lower-lying A-state within 20 ps or less, while the second step is a very fast decay from the A-state to the electronic ground state through a conical intersection. In addition we report the first zero kinetic energy (ZEKE) photoelectron spectrum of allyl, yielding an ionisation energy of 65762 cm(-1).
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DOI
10.1039/a909276e
ISSN
0301-7249
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PHY_Journal Papers
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