Synthesis of a Redox- Active Denpol as a Potential Electrode in Rechargeable Organic Batteries
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- Synthesis of a Redox- Active Denpol as a Potential Electrode in Rechargeable Organic Batteries
- Kim, Jonggi; Kim, Jieun; Lee, Jungho; Song, Hyun-Kon; Yang, Changduk
- Issue Date
- WILEY-V C H VERLAG GMBH
- CHEMELECTROCHEM, v.1, no.10, pp.1618 - 1622
- Together with ring-opening metathesis polymerization, a controlled protocol of a progressive addition of the ultrafast-initiating and more reactive third-generation Grubbs catalyst yields a dendronized polymer (denpol) containing multi-anthraquinone-terminated dendrons (AQ-ter-denpol) (M-n=14.0kDa) with a unimodal molar mass distribution (polydispersity index=1.20), fully characterized by (1)Hnuclear magnetic resonance spectroscopy. AQ-ter-denpol is investigated as an organic cathode material for rechargeable Li-ion batteries, with a view to its unique morphology. Our methodologies establish an opportunity for developing a new generation of organic electrodes based on denpols.
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