Fibrillation of PTFE binders during dry electrode manufacturing is influenced by multiple factors such as applied shear force, particle interactions, and binder crystallinity. However, the fundamental material properties governing this behavior remain poorly understood. In this study, DSC, Raman spectroscopy, and solid-state 19F NMR were employed to investigate properties of PTFE binders. These analyses provide a molecular-level understanding of PTFE binder characteristics potentially related to fibrillation behavior in dry electrode processing