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Ryu, Ja-Hyoung
Supramolecular NanoMaterials Lab (SUN)
Research Interests
  • Supramolecular assembly, synthetic peptide assembly, cancer drug delivery

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Aqueous self-assembly of aromatic rod building blocks

Cited 177 times inthomson ciCited 158 times inthomson ci
Title
Aqueous self-assembly of aromatic rod building blocks
Author
Ryu, Ja-HyoungHong, Dong-JeLee, Myongsoo
Keywords
PEPTIDE-AMPHIPHILE NANOFIBERS; LIQUID-CRYSTALLINE ASSEMBLIES; HEXA-PERI-HEXABENZOCORONENE; COIL MOLECULES; DIBLOCK COPOLYMERS; SUPRAMOLECULAR CHEMISTRY; HEXAGONAL COLUMNAR; GOLD NANOPARTICLES; ORGANIZATION; WATER
Issue Date
2008
Publisher
ROYAL SOC CHEMISTRY
Citation
CHEMICAL COMMUNICATIONS, v., no.9, pp.1043 - 1054
Abstract
One of the most fascinating subjects in areas such as nanoscience and biomimetic chemistry is concerned with the construction of novel supramolecular nanoscopic architectures with well defined shapes and functions. Supramolecular assemblies of aromatic rod molecules provide a facile entry into this area. Aromatic rigid rod molecules consisting of hydrophilic flexible chains, in aqueous solution can self-assemble into a variety of supramolecular structures through mutual interactions between aromatic rod molecules and water, including hydrophobic and hydrophilic interactions and π-π interaction. The supramolecular architecture in water can be manipulated by variation of the shape of the rigid segments, as well as the relative volume fraction of the flexible segment. The rigid aromatic segments have significant photonic and electronic properties. The self-assembly of aromatic rod molecules in water, therefore, can provide a strategy for the construction of well-defined and stable nanometer-size structures with chemical functionalities and physical properties as advanced materials for photonic, electronic and biological applications.
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DOI
10.1039/b713737k
ISSN
1359-7345
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PHY_Journal Papers
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