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Kim, Kyoung Taek
KT Kim Group at UNIST
Research Interests
  • Polymer Chemistry
  • Organic Chemistry
  • Supramolecular Chemistry
  • Biopolymers

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Organometallic-polypeptide block copolymers: Synthesis and properties of poly(ferrocenyldimethylsilane)-b-poly- (gamma-benzyl-L-glutamate)

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Title
Organometallic-polypeptide block copolymers: Synthesis and properties of poly(ferrocenyldimethylsilane)-b-poly- (gamma-benzyl-L-glutamate)
Author
Kim, Kyoung TaekVandermeulen, GWMWinnik, MAManners, I
Keywords
CONTAINING POLYMERS; MATERIALS SCIENCE; POLYMERIZATION; TRANSITION; NANOTUBES; VESICLES; MICELLES; PHASE; COIL; COMPLEXES
Issue Date
2005-06
Publisher
AMER CHEMICAL SOC
Citation
MACROMOLECULES, v.38, no.12, pp.4958 - 4961
Abstract
The synthesis and structural characterization of the first organometallic-polypeptide block copolymers, poly(ferrocenyldimethylsilane)-b-poly-(γ-benzyl-L-glutamate) was performed. The deprotection of the material to form the water-soluble organometallic-polypeptide block copolymers, PFS-b-poly(L-glutamic acid) (PFS-b-PGA) was also discussed. The macroinitiator PFS-NH2 was used for the ROP of γ-benzyl-L-glutamate NCA to obtain the organometallic-peptide block copolymers. The 1H NMR of the purified PFS-NH2 in C6D6 showed a signal at 2.47 ppm, which corresponded to the methylene protons adjacent to the terminal amino group.
URI
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DOI
10.1021/ma050336z
ISSN
0024-9297
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PHY_Journal Papers
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