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- Rohde, Jan-Uwe
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Regioselective Transformations of Unsaturated Systems Catalyzed by Low-Valent Nickel: Cycloaddition, Hydrosilylation, and Dicarbofunctionalization
- Author(s)
- Kim, Gun Ha, Jeon, Ji Hwan, Jung, Byunghyuck, Rohde, Jan-Uwe, Hong, Sung You
- Issued Date
- 2025-06
- Citation
- SYNLETT, v.36, no.13, pp.1889 - 1899
- Abstract
- In this Account, we describe our recent research progress in the development of the functionalization of unsaturated substrates catalyzed by low-valent nickel. In particular, we discuss nickel-catalyzedazide-alkyne cycloaddition (NiAAC), [2 + 2 + 2] cycloaddition of diynesand nitriles, hydrosilylation of alkynes, and dicarbo functionalization of1,3-enynes. Moreover, we highlight our mechanistic studies aimed at elucidating catalytically active nickel intermediates, thereby contributing to the understanding and expansion of nickel-catalyzed synthetic methodologies.
- Publisher
- GEORG THIEME VERLAG KG
- ISSN
- 0936-5214
- Keyword (Author)
- cycloaddition, nickel, hydrosilylation, dicarbofunctionalization, regioselectivity, reaction mechanisms, unsaturated systems
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