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Lim, Mi Hee
MetalloNeuroChemistry Lab (MNCL)
Research Interests
  • Neurodegenerative disease, small molecule design, network between metal, proteins, and ROS

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Temperature effect on the epoxidation of olefins by an iron(III) porphyrin complex and tert-alkyl hydroperoxides

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Title
Temperature effect on the epoxidation of olefins by an iron(III) porphyrin complex and tert-alkyl hydroperoxides
Author
Nam, WOh, SYLim, Mi HeeChoi, MHHan, SYJhon, GJ
Keywords
FREE-RADICAL MECHANISMS; T-BUOOH; ALKYLBENZENES; CHEMISTRY; CATALYSIS; OXIDATION; CLEAVAGE; SOLVENT; ALKANES; ALKENES
Issue Date
2000
Publisher
ROYAL SOC CHEMISTRY
Citation
CHEMICAL COMMUNICATIONS, v., no.18, pp.1787 - 1788
Abstract
An electron-deficient iron porphyrin complex catalyzes the epoxidation of olefins by tert-alkyl hydroperoxides via radical-free oxidation reactions in aprotic solvent; the epoxidation reactions were markedly influenced by reaction temperature and high yields of epoxide products were obtained with retention of stereospecificity at low temperature.
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DOI
10.1039/b005162o
ISSN
1359-7345
Appears in Collections:
PHY_Journal Papers
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