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Lim, Mi Hee
MetalloNeuroChemistry Lab (MNCL)
Research Interests
  • Neurodegenerative disease, small molecule design, network between metal, proteins, and ROS

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Remarkable anionic axial ligand effects of iron(III) porphyrin complexes on the catalytic oxygenations of hydrocarbons by H2O2 and the formation of oxoiron(IV) porphyrin intermediates by m-chloroperoxybenzoic acid

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Title
Remarkable anionic axial ligand effects of iron(III) porphyrin complexes on the catalytic oxygenations of hydrocarbons by H2O2 and the formation of oxoiron(IV) porphyrin intermediates by m-chloroperoxybenzoic acid
Author
Nam, WLim, Mi HeeOh, SYLee, JHLee, HJWoo, SKKim, CShin, W
Keywords
enzyme models; heme proteins; O-O activation; oxygenations; porphyrinoids
Issue Date
2000-10
Publisher
WILEY-V C H VERLAG GMBH
Citation
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.39, no.20, pp.3646 - 3649
Abstract
A marked influence on the catalytic epoxidation and hydroxylation of hydrocarbons by aqueous 30 % H2O2 in an aprotic solvent and on the formation of oxoiron(IV) porphyrin intermediates in m-chloroperoxybenzoic acid (m-CPBA) reactions in polar solvent is shown by the anionic axial ligands of an electron-deficient iron(III) porphyrin complex [Fe(tpfpp)X] (tpfpp=meso-tetrakis(pentafluorophenyl)porphinato dianion; see scheme).
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DOI
10.1002/1521-3773(20001016)39:20<3646::AID-ANIE3646>3.0.CO;2-Q
ISSN
1433-7851
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PHY_Journal Papers
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