Methoxy[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porphyrinato]-iron(III), [Fe(TDFPP)(OCH3)]
- Author(s)
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Kim, Y, Nam, W, Lim, Mi Hee, Jin, SW, Lough, AJ, Kim, SJ
- Issued Date
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2001-05
- DOI
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10.1107/S0108270101003006
- URI
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https://scholarworks.unist.ac.kr/handle/201301/8666
- Fulltext
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http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0035324551
- Citation
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ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, v.57, pp.556 - 557
- Abstract
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The crystal structure of the title compound, [Fe(C44H20F8N4)- (CH3O)], has been determined. The Fe atom lies 0.485 (1) ,A out of the plane of the four N atoms to which it is coordinated and from the inversion centre at the origin of the unit cell. The methoxy group is axially coordinated to the Fe atom with O-Fe-N angles of 106.3 (2) and 102.4 (2)°, a C-O-Fe angle of 128.3 (5)° and an Fe-O distance of 1.788 (5) A. Difluorophenyl rings are tilted from the porphyrin (por) plane with torsion angles of -68.1 (6) and 77.7 (5)° across the two Cpor-C-C-Car systems.
- Publisher
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WILEY-BLACKWELL
- ISSN
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0108-2701
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