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- Rohde, Jan-Uwe
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Reversible formation of iodosylbenzene-iron porphyrin intermediates in the reaction of oxoiron(IV) porphyrin pi-cation radicals and iodobenzene
- Author(s)
- Nam, W, Choi, SK, Lim, Mi Hee, Rohde, Jan-Uwe, Kim, I, Kim, J, Kim, C, Que, L
- Issued Date
- 2003
- Citation
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.42, no.1, pp.109 - 111
- Abstract
- The electronic nature of iron porphyrin complexes and iodobenzene derivatives markedly influences the formation of iodosylbenzene-iron(III) porphyrin intermediates 2, which are generated in the reaction of oxoiron(IV) porphyrin cation radicals 1 and iodobenzene. Epoxidation of olefins by 2 affords high yields of epoxide products.
- Publisher
- WILEY-V C H VERLAG GMBH
- ISSN
- 1433-7851
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