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Rohde, Jan-Uwe
Transition Metal Chemistry
Research Interests
  • Inorganic chemistry, coordination chemistry, organometallic chemistry, chemical synthesis, catalysis, green chemistry, inorganic reaction mechanisms.

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Self-hydroxylation of perbenzoic acids at a nonheme iron(II) center

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Title
Self-hydroxylation of perbenzoic acids at a nonheme iron(II) center
Author
Oh, NYSeo, MSLim, Mi HeeConsugar, MBPark, MJRohde, Jan-UweHan, JHKim, KMKim, JQue, LNam, W
Keywords
FE-IV=O COMPLEX; AROMATIC HYDROXYLATION; DIOXYGEN ACTIVATION; SPECTROSCOPIC CHARACTERIZATION; ENZYMES; OXYGEN; OXIDATION; LIGAND; INTERMEDIATE; MECHANISMS
Issue Date
2005-12
Publisher
ROYAL SOC CHEMISTRY
Citation
CHEMICAL COMMUNICATIONS, v., no.45, pp.5644 - 5646
Abstract
Treatment of mononuclear nonheme iron(II) complexes bearing two cis-labile sites with perbenzoic acids results in the self-hydroxylation of the aromatic ring to form the corresponding iron(III)-salicylate complexes through an intramolecular oxotransfer process.
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DOI
10.1039/b511302d
ISSN
1359-7345
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PHY_Journal Papers
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