Hybridizing Fabrications of Gd-CeO2 Thin Films Prepared by EPD and SILAR-A plus for Solid Electrolytes

Abstract

Thin films of gadolinium-doped ceria (GDC) nanoparticles were fabricated as electrolytes for low-temperature solid oxide fuel cells (SOFCs) by combining electrophoretic deposition (EPD) and the successive ionic layer adsorption and reaction-air spray plus (SILAR-A+) method. The Ce1-xGdxO2-x/2 solid solution was synthesized using hydrothermal (HY) and solid-state (SS) procedures to produce high-quality GDC nanoparticles suitable for EPD fabrication. The crystalline structure, cell parameters, and phases of the GDC products were analyzed using X-ray diffraction. Variations in oxygen vacancy concentrations in the GDC samples were achieved through the two synthetic methods. The ionic conductivities of pressed pellets from the HY, SS, and commercial G0.2DC samples, measured at 150 degrees C, were 0.6 x 10-6, 2.6 x 10-6, and 2.9 x 10-6 S/cm, respectively. These values were determined using electrochemical impedance spectroscopy (EIS) with a simplified equivalent circuit method. The morphologies of G0.2DC thin films prepared via EPD and SILAR-A+ processes were characterized, with particular attention to surface cracking. Crack-free GDC thin films, approximately 730-1200 nm thick, were successfully fabricated on conductive substrates through the hybridization of EPD and SILAR-A+, followed by hydrothermal annealing. EIS and ionic conductivity (1.39 x 10-9 S/cm) measurements of the G0.2DC thin films with thicknesses of 733 nm were performed at 300 degrees C.