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Moon, Hoi Ri
Functional Inorganic Nanomaterials for Energy Lab (FINE)
Research Interests
  • Inorganic-organic hybrid materials, carbon capture materials, hydrogen storage materials, heterogeneous catalyst

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Redox-active porous metal-organic framework producing silver nanoparticles from Ag-I ions at room temperature

Cited 158 times inthomson ciCited 149 times inthomson ci
Title
Redox-active porous metal-organic framework producing silver nanoparticles from Ag-I ions at room temperature
Author
Moon, Hoi RiKim, JHSuh, MP
Keywords
Coordination polymers; Host-guest systems; Microporous materials; Nanostructures; Silver
Issue Date
2005
Publisher
WILEY-V C H VERLAG GMBH
Citation
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.44, no.8, pp.1261 - 1265
Abstract
Hi ho silver! Coordination polymer chains assembled from a NiII hexaazamacrocycle and sodium 4,4′-biphenyldicarboxylate can be packed to form a porous framework (see picture). Nanocomposites of silver particles and matrix can be prepared by immersing the framework in AgNO3 solution, and the matrix-free silver nanoparticles (≈3 nm) isolated by treatment of the solid with boiling dioctyl ether containing oleic acid.
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DOI
10.1002/anie.200461408
ISSN
1433-7851
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PHY_Journal Papers
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