Redox-active porous metal-organic framework producing silver nanoparticles from Ag-I ions at room temperature
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- Redox-active porous metal-organic framework producing silver nanoparticles from Ag-I ions at room temperature
- Moon, Hoi Ri; Kim, JH; Suh, MP
- Coordination polymers; Host-guest systems; Microporous materials; Nanostructures; Silver
- Issue Date
- WILEY-V C H VERLAG GMBH
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.44, no.8, pp.1261 - 1265
- Hi ho silver! Coordination polymer chains assembled from a NiII hexaazamacrocycle and sodium 4,4′-biphenyldicarboxylate can be packed to form a porous framework (see picture). Nanocomposites of silver particles and matrix can be prepared by immersing the framework in AgNO3 solution, and the matrix-free silver nanoparticles (≈3 nm) isolated by treatment of the solid with boiling dioctyl ether containing oleic acid.
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