BROWSE

Related Researcher

Author's Photo

Moon, Hoi Ri
Functional Inorganic Nanomaterials for Energy Lab (FINE)
Research Interests
  • Inorganic-organic hybrid materials, carbon capture materials, hydrogen storage materials, heterogeneous catalyst

ITEM VIEW & DOWNLOAD

Self-assembly of hybrid solids consisting of 2D supramolecular networks and intercalated metal complexes

Cited 3 times inthomson ciCited 4 times inthomson ci
Title
Self-assembly of hybrid solids consisting of 2D supramolecular networks and intercalated metal complexes
Author
Suh, MPJeon, JWMoon, Hoi RiMin, KSChoi, HJ
Keywords
2D network; Chromium oxalate; Copper complex; Hybrid compounds; Intercalation; Nickel macrocycle; Self-assembly
Issue Date
2005-09
Publisher
ELSEVIER FRANCE-EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
Citation
COMPTES RENDUS CHIMIE, v.8, no.9-10, pp.1543 - 1551
Abstract
Hybrid compounds [NaCr(ox)3]2 [Ni(cyclam)][Ni(cyclam)(H2O)2]·8 H2O (1) and [NaCr(ox)3][Cu(tren)(H2 O)]·3 H2O (2) are assembled in MeCN/H2O from the reaction of Na3[Cr(ox)3]·5 H2O with [Ni(cyclam)](ClO4)2 and [Cu(tren)](PF6)2, respectively, where cyclam = 1,4,8,11-tetraazacyclotetradecane and tren = tris(2-aminoethyl)amine. In 1 and 2, Ni(II) macrocyclic complex and Cu(II) complex, respectively, are intercalated between the anionic 2D layers of [NaCr(ox)3] n 2n-. The magnetic susceptibility data of 1 and 2, measured in the temperature range 5-301K, indicate weak ferromagnetic interactions (θ = 1.9 K for 1 and 0.29 K for 2) between the Cr(III) ions in the 2D layers and the intercalated paramagnetic metal complexes.
URI
Go to Link
DOI
10.1016/j.crci.2004.10.034
ISSN
1631-0748
Appears in Collections:
PHY_Journal Papers
Files in This Item:
2-s2.0-26944470725.pdf Download

find_unist can give you direct access to the published full text of this article. (UNISTARs only)

Show full item record

qrcode

  • mendeley

    citeulike

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

MENU