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Moon, Hoi Ri
Functional Inorganic Nanomaterials for Energy Lab (FINE)
Research Interests
  • Inorganic-organic hybrid materials, carbon capture materials, hydrogen storage materials, heterogeneous catalyst

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A Stair-Shaped Molecular Silver(0) Chain

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Title
A Stair-Shaped Molecular Silver(0) Chain
Author
Moon, Hoi RiChoi, Cheol HoSuh, Myunghyun Paik
Issue Date
2008
Publisher
WILEY-V C H VERLAG GMBH
Citation
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.47, no.44, pp.8390 - 8393
Abstract
Bound in chains: The molecular Ag0 chain [Ag4py 2]n (py=C5H5N) is formed from two covalently linked infinite zigzag chains of Ag, in which Ag-Ag bonds alternate between long and short (see picture; blue Ag, gray C, orange N). Theoretical calculations indicate that partially positively (+0.35) and negatively (-0.30) charged Ag atoms are alternately located along the chain, which has a bandgap of 4.1 eV. (Figure Presented)
URI
https://scholarworks.unist.ac.kr/handle/201301/8460
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=54249128211
DOI
10.1002/anie.200803465
ISSN
1433-7851
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CHM_Journal Papers
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